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青貯飼料近紅外光譜分析模型轉(zhuǎn)移研
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Transfer of NIRS on Silage by Slope/Bias and Local Centering Technique
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    為了探討青貯飼料的近紅外光譜(NIRS)分析模型在不同類型光譜儀器之間的轉(zhuǎn)移,以傅里葉變換型近紅外光譜儀Nicolet ANTARIS作為主儀器,光柵型近紅外光譜儀FOSS 6500作為從儀器,采用斜率/截距和局部中心化2種方法進(jìn)行了研究。結(jié)果表明,經(jīng)斜率/截距和局部中心化法轉(zhuǎn)移之后,所建立校正模型的決定系數(shù)R2和交互驗(yàn)證決定系數(shù)R2cv均大于0.85。采用斜率/截距法轉(zhuǎn)移之后,ANTARIS儀器校正模型對(duì)FOSS 6500儀器驗(yàn)證集的預(yù)測(cè)標(biāo)準(zhǔn)差為20.27g/kg,系統(tǒng)偏差為-3.75,采用局部中心化法轉(zhuǎn)移之后的預(yù)測(cè)標(biāo)準(zhǔn)差為27.67g/kg,系統(tǒng)偏差為-6.17。2種方法模型轉(zhuǎn)移后的預(yù)測(cè)結(jié)果與FOSS 6500儀器模型的預(yù)測(cè)結(jié)果(預(yù)測(cè)標(biāo)準(zhǔn)差為20.60g/kg,系統(tǒng)偏差為-1.04)非常接近,比轉(zhuǎn)移前的預(yù)測(cè)結(jié)果(預(yù)測(cè)標(biāo)準(zhǔn)差為39.65g/kg,系統(tǒng)偏差為-33.60)有較大程度改善,2種方法均獲得較好的轉(zhuǎn)移效果。

    Abstract:

    With the aim to demonstrate the feasibility of calibration transfer of near-infrared spectroscopy on silage, two types of near-infrared spectrometer of Nicolet ANTARIS (master) and FOSS 6500 (slave), and two methods of slope/bias and local centering were studied. Results show that after calibration transferring the determination coefficient of calibration (R2) and determination coefficient of cross validation (R2cv) were all greater than 0.85. The standard error of prediction and bias were 20.27g/kg and -3.75, 27.67g/kg and -6.17 for slope/bias and local centering technique respectively, which were comparable with the standard error of prediction value (20.60g/kg) and bias value (-1.04) of the original model of FOSS 6500 spectrometer. These results were greatly improved from the standard error of prediction value (39.65g/kg) and bias value (-33.60) before calibration transferring. Both of the two methods of calibration transfer worked successfully.

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劉賢,董蘇曉,韓魯佳,楊增玲,徐春城.青貯飼料近紅外光譜分析模型轉(zhuǎn)移研[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2009,40(5):153-157. Transfer of NIRS on Silage by Slope/Bias and Local Centering Technique[J]. Transactions of the Chinese Society for Agricultural Machinery,2009,40(5):153-157.

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