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硫酸鹽黑液直接苛化與水蒸氣氣化研究
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國(guó)家自然科學(xué)基金資助項(xiàng)目(50876109);國(guó)家高技術(shù)研究發(fā)展計(jì)劃(863計(jì)劃)資助項(xiàng)目(2007AA05Z410);中科院廣州能源研究所所長(zhǎng)創(chuàng)新基金資助項(xiàng)目(0807z11001)


Kraft Black Liquor Steam Gasification with Direct Causticization
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    摘要:

    采用銳鈦礦型二氧化鈦對(duì)兩種硫酸鹽黑液半焦在860℃的溫度下進(jìn)行了直接苛化與水蒸氣氣化實(shí)驗(yàn)。結(jié)果表明:黑液半焦中的有機(jī)碳可在6min內(nèi)氣化完畢,直接苛化反應(yīng)也可在此時(shí)間內(nèi)完成;氣化所得氣體的干基高位熱值約10MJ/m3;氣化與直接苛化所得固體產(chǎn)物熔點(diǎn)高于900℃且粉末狀態(tài)良好,主要成分為五鈦酸鈉,該產(chǎn)物水解后生成氫氧化鈉和不易繼續(xù)水解的三鈦酸鈉;回收的三鈦酸鈉繼續(xù)用于直接苛化實(shí)驗(yàn)時(shí),固體產(chǎn)物沒(méi)有發(fā)生結(jié)塊現(xiàn)象,可以循環(huán)利用;約占黑液總硫20%的硫以非還原態(tài)留存于氣化殘余固體中。

    Abstract:

    Steam gasification of kraft black liquor char was performed at 860℃ in a tube furnace with direct causticization using anatase titanium dioxide and recycled sodium tri-titanate. The organic carbon in the black liquor char could be completely gasified within 6 min, approximately equal to the complete conversion time of sodium carbonate in black liquor char to sodium penta-titanate at these conditions, and the generated dry gas had a high heating value of nearly 10MJ/m3. The main component of solid product was sodium penta-titanate, and the sodium tri-titanate recycled from hydrolysis of sodium penta-titanate had satisfactory reactivity compared to fresh titanium dioxide. No agglomeration of solid product was observed through the process of reactions. About 20% of total sulfur in black liquor retained in the gasified residual solid in the form of non-reduced state.

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袁洪友,陰秀麗,李志文,周肇秋,吳創(chuàng)之.硫酸鹽黑液直接苛化與水蒸氣氣化研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2011,42(8):117-121. Yuan Hongyou, Yin Xiuli, Li Zhiwen, Zhou Zhaoqiu, Wu Chuangzhi. Kraft Black Liquor Steam Gasification with Direct Causticization[J]. Transactions of the Chinese Society for Agricultural Machinery,2011,42(8):117-121.

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