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有機胺基氨基酸鹽吸收劑的沼氣CO2分離特性
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國家自然科學基金資助項目(51006044、51376078)和中央高?;究蒲袠I(yè)務費專項資金資助項目(2011PY007)


Performance of CO2 Removal from Biogas by Using Amine-based Amino Acid Salts
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    摘要:

    在鼓泡式CO2吸收和再生裝置中對有機胺基氨基酸鹽吸收劑的沼氣CO2吸收和再生特性進行了研究,并與乙醇胺(MEA)和哌嗪(PZ)進行了對比。試驗中,氣相為典型的模擬沼氣氛圍(CO2與CH4體積分數比為4∶6,常壓),液相CO2吸收溫度為35℃,再生溫度為75℃,并輔以純CH4作為吹掃氣。結果表明:當達到CO2吸收和再生平衡時,質量分數為30%的4種乙醇胺基氨基酸鹽吸收劑對CO2的凈攜帶容量均優(yōu)于MEA,且乙醇胺基鳥氨酸鹽(MEAORN)的CO2凈攜帶容量最高(0.733 mol/mol),比第二位、質量分數為15%的PZ高82.34%。同時,綜合考慮能耗與投資成本,對吸收劑CO2分離成本的對比分析表明,MEAORN和PZ的沼氣CO2分離成本低于MEA,而乙醇胺基氨基乙酸鹽(MEAGLY)在大規(guī)模沼氣提純上具有替代MEA進行工程應用的潛能。

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    Amine based amino acid salts were investigated in this study by using a bubbling CO2 absorption and regeneration reactor to assess their CO2 absorption performance from the simulated biogas and regeneration characteristics. In addition, monoethanolamine (MEA) and piperazine (PZ) were also experimented to compare with these amine based amino acid salts. In the experiments, the typical biogas consisting of 40% CO2 and 60% CH4 was used under the ambient circumstance, while 35℃ and 75℃ were adopted to act as the absorption and regeneration temperatures of solvents, respectively. And pure CH4 was also used to act as the sweeping gas during CO2 regeneration stage. The results showed that when the equilibrium CO2 absorption and regeneration statuses were reached, the net CO2 cyclic capacities of all the four MEA-based amino acid salts were higher than MEA, and MEA-based L-ornithinate (MEAORN) with 30% weight fraction owned the highest value (about 0.733 mol/mol), which was approximate 82.43% higher than PZ with 15% weight fraction gaining the second higher CO2 cyclic capacity. Furthermore, CO2 removal costs from biogas of different absorbents were assessed and compared when considering the regeneration energy consumption and investment of absorber and desorber. Results showed that no matter the scale of CO2 absorption plant was taken into application, the CO2 removal costs of MEAORN and PZ might be less than MEA. And MEAGLY might have the potential to act as the most promising alternative to replace MEA in the large-scale biogas upgrading plants. 

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晏水平,賀清堯,蔡凱,艾平,王媛媛,張衍林.有機胺基氨基酸鹽吸收劑的沼氣CO2分離特性[J].農業(yè)機械學報,2014,45(6):199-205. Yan Shuiping, He Qingyao, Cai Kai, Ai Ping, Wang Yuanyuan, Zhang Yanlin. Performance of CO2 Removal from Biogas by Using Amine-based Amino Acid Salts[J]. Transactions of the Chinese Society for Agricultural Machinery,2014,45(6):199-205.

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  • 收稿日期:2013-05-22
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  • 在線發(fā)布日期: 2014-06-10
  • 出版日期: 2014-06-10