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砒砂巖改良風(fēng)沙土對(duì)銨態(tài)氮吸附特性影響研究
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中國科學(xué)院西部行動(dòng)計(jì)劃資助項(xiàng)目(KZCX2-XB3-13-02)和教育部新世紀(jì)優(yōu)秀人才支持計(jì)劃資助項(xiàng)目(NCET-13-0487)


Effects of Soft Rock Modified Sandy Soil on NH+4 N Adsorption Characteristics
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    摘要:

    由于砒砂巖的廣泛分布和煤炭資料的開發(fā)利用,晉陜蒙接壤區(qū)出現(xiàn)了一系列生態(tài)環(huán)境問題。為恢復(fù)區(qū)域生態(tài),嘗試?yán)脜^(qū)域內(nèi)的砒砂巖來改良風(fēng)沙土,以實(shí)現(xiàn)砒砂巖的資源化利用和受損生態(tài)系統(tǒng)的修復(fù),本研究設(shè)計(jì)了風(fēng)沙土中砒砂巖不同添加比例(0、10%、25%、50%、75%、90%、100%)的改良模式。研究了25℃下不同改良模式對(duì)NH+4 N吸附動(dòng)力學(xué)和等溫吸附特征的影響,評(píng)價(jià)了不同模型對(duì)改良土壤的適應(yīng)性,以期為建立合理的氮肥施用指標(biāo)和提高肥料利用率提供依據(jù)。結(jié)果表明:相同條件下,砒砂巖對(duì)NH+4 N的吸附量大于風(fēng)沙土;隨著砒砂巖添加比例的增加,改良土壤對(duì)NH+4 N的吸附量呈線性增加關(guān)系。砒砂巖的添加可以顯著增加風(fēng)沙土對(duì)NH+4 N的吸附,增加土壤供氮的持續(xù)性,提高肥料的有效性。準(zhǔn)二級(jí)動(dòng)力學(xué)模型可用于擬合改良土壤對(duì)NH+4 N的吸附動(dòng)力學(xué)曲線。NH+4 N的等溫吸附曲線以Freundlich模型擬合效果更優(yōu)。各處理對(duì)NH+4N的吸附均為自發(fā)過程,且為有利吸附,吸附速率由膜擴(kuò)散和顆粒內(nèi)擴(kuò)散共同控制。

    Abstract:

    Due to the widely existence of soft rock and the exploitation of coal resource, serious ecological and environmental problems occurred in the contiguous areas of Shanxi, Shaanxi and Inner Mongolia in China. In order to restore regionally ecological environment, this study was conducted to improve sandy soil using soft rock in the energy communities, and realize the transformation of soft rock into available resources. Previous research found that soft rock could improve hydraulic properties of sandy soil. But there are few researches about the nutrient availability of soft rock distributed into sandy soil. Soft rock was mixed in sandy soil with seven ratios: 0,10%,25%,50%,75%,90% and 100%. Adsorption kinetic were determined and fitted with Freundlich,Langmuir,Temkin and DubininRadushkevich models. Adsorption isotherms were measured and modeled with Pseudofirstorder, Pseudosecondorder, Biconstant and Intraparticle diffusion models. This study was conducted to understand the effects of different additive proportions of soft rock amended sandy soils on the adsorption of NH+4 N, and to select the optimal adsorption model of improved soil. The results can be used to guide reasonable fertilization of nitrogenous and improve the utilization efficiency of fertilize. The results showed that: with the extension of reaction times and the increase of equilibrium concentration, the NH+4 N adsorption capacity was increased in improved soil. Reaching to the adsorption equilibrium, sandy soil needs 4 hours and soft rock needs 16 hours. Adsorption capacity of NH+4 N was the largest in sandy soil and the least in soft rock, the maximum adsorption of NH+4 N in soft rock was 20 times of sand soil. With the increase of the soft rock proportion in improved soil, NH+4 N optimal adsorption was increased linearly. Soft rock could improve the NH+4 N adsorption capacity of sandy soil. The pseudosecondorder kinetic model and the Freundlich isotherm model could well describe NH+4 N absorption in improved soil. NH+4 N adsorption is a spontaneous process and a favorable adsorption.

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攝曉燕,魏孝榮,魏艷春,馬天娥,許晶晶,張興昌.砒砂巖改良風(fēng)沙土對(duì)銨態(tài)氮吸附特性影響研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2015,46(11):165-173. She Xiaoyan, Wei Xiaorong, Wei Yanchun, Ma Tiane, Xu Jingjing, Zhang Xingchang. Effects of Soft Rock Modified Sandy Soil on NH+4 N Adsorption Characteristics[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(11):165-173.

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  • 收稿日期:2015-06-07
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  • 在線發(fā)布日期: 2015-11-10
  • 出版日期: 2015-11-10