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松木屑成型顆粒制備富氫產(chǎn)品氣試驗(yàn)研究
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內(nèi)蒙古自然科學(xué)基金資助項(xiàng)目(2015MS0106)和內(nèi)蒙古科技創(chuàng)新引導(dǎo)獎(jiǎng)勵(lì)計(jì)劃資助項(xiàng)目(01850401)


Experimental Study on Preparation of Hydrogen-rich Gas from Pine Sawdust Pellets
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    摘要:

    基于生物質(zhì)氣化技術(shù),采用下吸式氣化爐為反應(yīng)器,以高溫水蒸氣作為氣化劑,選取溫度和S/B(水蒸氣流量與生物質(zhì)氣化量比)作為影響因素,爐體溫度的變化范圍700~950℃,S/B取值范圍0.3~1.0,對產(chǎn)品氣的組分變化規(guī)律進(jìn)行分析,探討了爐內(nèi)的氣化反應(yīng)特性。試驗(yàn)結(jié)果表明,下吸式氣化爐碳層內(nèi)的水蒸氣氣化反應(yīng)及焦油裂解反應(yīng)對制取富氫燃?xì)庥兄匾饔茫?H2和CO的產(chǎn)率隨溫度的升高而增加,在溫度增加到一定值后,H2體積分?jǐn)?shù)達(dá)到峰值,繼續(xù)升高溫度導(dǎo)致H2的體積分?jǐn)?shù)有所下降。S/B的增加有利于產(chǎn)品氣中的H2含量的提升,但吸熱反應(yīng)造成爐內(nèi)床體的反應(yīng)溫度下降,抑制H2體積分?jǐn)?shù)的增加。在本試驗(yàn)條件下, H2的體積分?jǐn)?shù)最大達(dá)到47.67%,對應(yīng)的工況S/B為1.0,溫度為900℃。

    Abstract:

    Experimental results are presented on the gasification of pine sawdust pellets using high temperature steam as the gasification agent. Downdraft gasifier was adopted as reactor, the reactor temperature was varied from 700℃ to 950℃, and steam to biomass ratio (S/B) was changed from 0.3 to 1.0. Based on biomass gasification technology, the gasification characteristics of pine sawdust pellets were deeply discussed. In addition, numerical computation using Gibbs free energy minimization was applied and compared with the experimental results. The results show that hydrogenrich gas could be effectively produced by high temperature steam in downdraft gasifier, and the carbon layer played an important role in preparation of hydrogenrich gas, in which steam reforming reaction and tar cracking were taken place. H2 and CO yields would rise at higher temperature, and H2 volume fraction would reach the peak when reactor temperature raised some value,H2 fraction would decline if the temperature was continued to raise. The increase of S/B could develop H2 content of product gas, temperature of material bed would be dropped by some endothermic reactions, and the increase of H2 volume fraction was restrained. In the test, the peak value of H2 volume fraction was 47.67% with S/B of 1.0 and temperature of 900℃. These results also provide the operating law for downdraft gasifier with high temperature steam.

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龐赟佶,沈勝強(qiáng),陳義勝,馬黎軍,王宏坤.松木屑成型顆粒制備富氫產(chǎn)品氣試驗(yàn)研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2015,46(11):208-213. Pang Yunji, Shen Shengqiang, Chen Yisheng, Ma Lijun, Wang Hongkun. Experimental Study on Preparation of Hydrogen-rich Gas from Pine Sawdust Pellets[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(11):208-213.

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  • 收稿日期:2015-06-04
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  • 在線發(fā)布日期: 2015-11-10
  • 出版日期: 2015-11-10