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自動進樣與恒溫控制型電子舌檢測系統(tǒng)
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國家自然科學(xué)基金項目(31201368)


Electronic Tongue Detection System with Automatic Sampling and Constant Temperature Control
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    摘要:

    針對現(xiàn)有電子舌集成化、自動化程度較低的問題,設(shè)計了一臺能自動調(diào)節(jié)樣品溫度、進樣、清洗電極和檢測樣品的伏安型電子舌,包括上位機、控制模塊、電極與信號采集模塊、自動進樣模塊、恒溫槽模塊和按鍵顯示模塊。系統(tǒng)的控制界面基于LabVIEW設(shè)計開發(fā),通過串口向控制模塊發(fā)送指令,進而控制自動進樣、恒溫槽等模塊協(xié)同工作。電極與信號采集模塊采用了三電極檢測體系,由貴金屬裸電極陣列、調(diào)理電路、采集卡構(gòu)成,運用脈沖伏安法獲得樣品的信號曲線,并與上位機之間通過USB互傳數(shù)據(jù)。對設(shè)備的進樣和調(diào)溫性能試驗結(jié)果表明,自動進樣模塊能可靠運行,恒溫槽對樣品的溫度控制范圍為(25±1)℃。對設(shè)備的檢測性能試驗表明,檢測信號特征值隨時間漂移較小,有良好的穩(wěn)定性。樣品溫度波動會引起特征值顯著變化,恒溫槽控溫能有效提高電子舌檢測精度。使用電子舌對不同類型的啤酒、牛奶、水和不同等級的茶葉4大類樣品進行檢測,對數(shù)據(jù)運用主成分分析(PCA),結(jié)果顯示電子舌對它們均能有效區(qū)分。

    Abstract:

    The electronic tongue has better stability and repeatability than sensory evaluation and it also has the advantages of easy-operated and faster detection speed relative to traditional equipments. At present, the research of electronic tongue is mainly focused on sensor development, and the research on system integration and automation is rare. Thus, a voltammetric electronic tongue was designed, which can automatically adjust the temperature of sample, feed into sample, clean the electrode and detect sample. It included the upper computer, control module, electrode, signal acquisition module, automatic sampling module, thermostatic bath module and display module, etc. The control interface was based on LabVIEW. The upper computer sent commands to control module to drive the automatic sampling module, thermostatic bath module and other modules through the serial port. Signal acquisition module connected the upper computer through USB cable. It contained a three electrodes system, and the signal curve of the sample was obtained by pulse voltammetry. The test results showed that all the modules were stable and reliable and the temperature control accuracy of the sample was (25±1)℃. The area between the signal curve and the X axis was used as the signal characteristic value. The drift of signal characteristic values of 20d was below 5.6%. The characteristic value was affected significantly by the sample temperature. When the sample temperature departure was ±5℃, the error of the characteristic value was 36%. Under the control of temperature bath (25±1)℃, the error of the characteristic value was 5.8%, which indicated that the temperature control can effectively improve the accuracy of electronic tongue detection result. In the detection application,the electronic tongue can distinguish among four different kinds of beer, milk, water and different grades of tea with the principal component analysis (PCA).

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任奇鋒,王俊.自動進樣與恒溫控制型電子舌檢測系統(tǒng)[J].農(nóng)業(yè)機械學(xué)報,2016,47(4):186-192. Ren Qifeng, Wang Jun. Electronic Tongue Detection System with Automatic Sampling and Constant Temperature Control[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(4):186-192.

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  • 收稿日期:2015-10-26
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  • 在線發(fā)布日期: 2016-04-10
  • 出版日期: 2016-04-10