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電解與紫外協(xié)同去除工廠化養(yǎng)殖循環(huán)水中氨氮效果研究
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“十二五”國(guó)家科技支撐計(jì)劃項(xiàng)目(2014BAD08B09)和浙江重點(diǎn)科技創(chuàng)新團(tuán)隊(duì)計(jì)劃項(xiàng)目(2011R50029)


Removal Effect of Ammonia in RAS Using Electrochemical Process Combined with UV Irradiation
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    摘要:

    為探究電化學(xué)氧化法在工廠化循環(huán)水養(yǎng)殖系統(tǒng)中處理水質(zhì)的效果及影響因素,在前期試驗(yàn)得到最佳條件(溫度25℃、電流密度40A/m2、水流速度300mL/min)下,以不同初始氨氮質(zhì)量濃度和固體懸浮顆粒物的模擬養(yǎng)殖水以及實(shí)際養(yǎng)殖水為研究對(duì)象,探討了加入低壓紫外汞燈后電解與紫外協(xié)同去除氨氮的效果。結(jié)果表明:電解紫外協(xié)同處理氨氮效果明顯優(yōu)于單獨(dú)電解法,運(yùn)用本系統(tǒng)處理氨氮初始質(zhì)量濃度分別為4、7、10mg/L的模擬養(yǎng)殖水時(shí),氨氮去除效率相對(duì)于單獨(dú)電解時(shí)分別提高45.0%(p<0.05)、36.0%(p<0.05)和20.0%(p<0.05);電解紫外協(xié)同去除氨氮效率受氨氮初始質(zhì)量濃度、水體中的固體顆粒懸浮物、實(shí)際養(yǎng)殖水等因素影響,隨著氨氮初始質(zhì)量濃度及水體中固體懸浮顆粒物的升高,氨氮的去除效率降低,達(dá)到同種去除效率所需的時(shí)間延長(zhǎng),當(dāng)處理固體懸浮顆粒(SS)分別為100、150、200mg/L的模擬養(yǎng)殖水時(shí),氨氮的去除效率隨著SS的升高而降低,相對(duì)于僅含氨氮的模擬養(yǎng)殖水,氨氮的去除效率分別降低51.7%(p<0.05)、65.5%(p<0.05)和72.4%(p<0.05);在處理實(shí)際養(yǎng)殖水時(shí),氨氮的去除速率明顯降低,去除完全所需的時(shí)間延長(zhǎng),在本系統(tǒng)中電解紫外對(duì)氨氮、亞硝氮、固體懸浮顆粒物的去除具有較好效果,去除率分別為97.8%、96.9%和92.1%。

    Abstract:

    To explore the effect of water treatment and the influencing factors by using the electrochemical oxidation process in industrial recirculating aquaculture system, the research was conducted under the best condition with temperature of 25℃, current density of 40A/m2 and flow rate of 300mL/min, which was obtained by the former study. With different initial concentrations of ammonia nitrogen, suspended solid of simulated aquaculture water and actual aquaculture water of tilapia from the recirculating aquaculture lab of Zhejiang University, the removal rate of ammonia nitrogen was explored by using electrochemical process combined with UV irradiation. It demonstrated that the effect of using electrochemical process combined with UV irradiation was much better than that of single use of electrochemical process. Therefore, under initial concentrations of ammonia nitrogen at 4mg/L, 7mg/L and 10mg/L of simulated aquaculture water, the removal rates of ammonia nitrogen were increased by 45.0% (p<0.05), 36.0% (p<0.05) and 20.0%(p<0.05), respectively. The initial concentration of ammonia nitrogen、the suspended solid in the aquaculture water and the actual aquaculture water had important effects on removal efficiency of ammonia nitrogen, with the increase of initial concentration of ammonia nitrogen and concentration of suspended solid, the removal efficiency was reduced and the spending time was prolonged. For example, the treatment of different simulated aquaculture water with suspended solid of 100mg/L, 150mg/L, 200mg/L, the removal rate of ammonia nitrogen was decreased with the increase of SS, compared with the simulated aquaculture water only containing ammonia nitrogen, the removal rates of ammonia nitrogen were decreased by 51.7% (p<0.05), 65.5% (p<0.05) and 72.4%(p<0.05), respectively. When dealing with actual aquaculture water, although the system had great effects on the removal of ammonia nitrogen (the efficiency was 97.8%), nitrate nitrogen (the efficiency was 96.9%) and suspended solid (the efficiency was 92.1%), the removal rate of ammonia nitrogen was decreased and the time spent was prolonged.

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吳照學(xué),李海軍,楊智良,裴洛偉,朱松明,葉章穎.電解與紫外協(xié)同去除工廠化養(yǎng)殖循環(huán)水中氨氮效果研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2016,47(4):272-279. Wu Zhaoxue, Li Haijun, Yang Zhiliang, Pei Luowei, Zhu Songming, Ye Zhangying. Removal Effect of Ammonia in RAS Using Electrochemical Process Combined with UV Irradiation[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(4):272-279.

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  • 收稿日期:2015-10-12
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  • 在線(xiàn)發(fā)布日期: 2016-04-10
  • 出版日期: 2016-04-10