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低?;Y(jié)冷膠/酪蛋白酸鈉復(fù)合體系液-固轉(zhuǎn)變流變學(xué)表征
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國(guó)家自然科學(xué)基金項(xiàng)目(51103131)、食品科學(xué)與工程浙江省重中之重一級(jí)學(xué)科開(kāi)放基金項(xiàng)目(JYTSP20142091)和浙江大學(xué)高分子合成與功能構(gòu)造教育部重點(diǎn)實(shí)驗(yàn)室項(xiàng)目(2015MSF002)


Rheological Characterization on Liquid-Solid Transition of Low Acyl Gellan/Sodium Caseinate Mixtures
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    摘要:

    采用流變學(xué)方法研究了低?;Y(jié)冷膠(LA)和酪蛋白酸鈉(SC)復(fù)合體系的液-固轉(zhuǎn)變,對(duì)比了儲(chǔ)能模量、損耗模量交點(diǎn)法和Winter準(zhǔn)則,并利用非等溫動(dòng)力學(xué)模型研究了LA/SC復(fù)合體系的結(jié)構(gòu)變化。結(jié)果表明,Winter準(zhǔn)則更適用于表征LA/SC復(fù)合體系的液-固轉(zhuǎn)變。對(duì)于LA/SC復(fù)合體系而言,酪蛋白酸鈉存在一個(gè)臨界質(zhì)量濃度0.005g/mL,當(dāng)體系內(nèi)酪蛋白酸鈉質(zhì)量濃度低于該臨界值時(shí),酪蛋白的添加對(duì)凝膠溫度影響不大,但當(dāng)酪蛋白酸鈉質(zhì)量濃度超過(guò)該臨界值時(shí),酪蛋白酸鈉的添加會(huì)顯著地降低復(fù)合體系的凝膠溫度。復(fù)合體系的松弛指數(shù)隨著酪蛋白濃度的升高呈先增大后降低的變化趨勢(shì),而分形維數(shù)則隨著酪蛋白濃度的升高呈先減小后增大的變化趨勢(shì)。非等溫動(dòng)力學(xué)研究結(jié)果表明,復(fù)合體系的凝膠可以分為2個(gè)階段。

    Abstract:

    The liquid-solid transition of low acyl gellan (LA) and sodium caseinate (SC) mixtures were investigated by using rheological measurements. The liquid-solid transition temperatures were determined from two criteria: the crossover of storage modulus G′ and loss modulus G″, and the Winter’s criterion. The results showed that the Winter’s criterion was more suitable to determine the sol-gel transition temperature. For LA/SC mixtures, there was a critical SC concentration (0.005g/mL ratio of mass to volume). The concentration of sodium caseinate almost had no influence on the gelation temperature of LA/SC mixtures at or below concentration of 0.005g/mL. While above 0.005g/mL, the gelation temperatures of LA/SC mixtures were decreased linearly with the increase of SC concentration. The relaxation critical exponent n can be determined by the Winter’s criterion. There was no universal n for the gelation in LA/SC mixed solutions, indicating that this gelation belonged to the cross-linking of existing macromolecules. And n increased with the increase of SC concentration until SC concentration reached a critical level, after which further increase in SC concentration resulted in a reduction of n. The fractal dimension df was calculated from n without the screened hydrodynamic interaction or the excluded volume effect and the trend of the change of the df was opposite to that of n. Using a non-isothermal kinetics model, active energy (Ea) during gelation was calculated. However, a discontinuity was observed in the activation energy plots. Based on this, two gelation mechanisms were presumed-association of low acyl gellan gum and sodium caseinate molecules and aggregation of polymer strands.

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陳青,馬慧婷,陸海霞,姚蘭英.低?;Y(jié)冷膠/酪蛋白酸鈉復(fù)合體系液-固轉(zhuǎn)變流變學(xué)表征[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2017,48(8):322-327. CHEN Qing, MA Huiting, LU Haixia, YAO Lanying. Rheological Characterization on Liquid-Solid Transition of Low Acyl Gellan/Sodium Caseinate Mixtures[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(8):322-327.

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  • 收稿日期:2016-12-16
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  • 在線發(fā)布日期: 2017-08-10
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