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電子束輻照前處理對(duì)梅魚(yú)魚(yú)糜凝膠揮發(fā)性成分的影響
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國(guó)家自然科學(xué)基金面上項(xiàng)目(31371793)、海洋公益性行業(yè)科研專項(xiàng)(201305013)和寧波大學(xué)學(xué)科項(xiàng)目(xkzsc1429)


Effects of Electron Beam Irradiation Pre-treatment on Volatile Flavor Components of Collichthys lucidus Surimi Gel
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    摘要:

    為分析電子束輻照對(duì)魚(yú)糜凝膠嗅感的影響,采用不同電子束輻照劑量處理梅魚(yú)魚(yú)糜,通過(guò)熱誘導(dǎo)形成魚(yú)糜凝膠,利用頂空固相微萃取-氣質(zhì)聯(lián)用(HS-SPME-GC-MS)、感官評(píng)定和電子鼻分析,結(jié)合相對(duì)氣味活度值研究輻照前處理對(duì)梅魚(yú)魚(yú)糜凝膠揮發(fā)性風(fēng)味的影響。結(jié)果表明:輻照組魚(yú)糜凝膠魚(yú)香味略有減弱,高劑量組(≥7kGy)稍有輻照異味;對(duì)照組與輻照組魚(yú)糜凝膠電子鼻風(fēng)味線性判別分析(LDA)圖區(qū)分明顯,其中3kGy和5kGy組、7kGy和9kGy組有重疊,說(shuō)明2組間揮發(fā)性風(fēng)味相似;輻照后魚(yú)糜凝膠揮發(fā)性成分種類增加,含有更高含量的烴類、醛類和酮類物質(zhì);梅魚(yú)魚(yú)糜凝膠最關(guān)鍵的嗅感成分為癸醛、1-辛烯-3-醇、3-甲基丁醛、2,3-辛二酮等物質(zhì),低劑量(≤5kGy)輻照對(duì)魚(yú)糜凝膠嗅感起關(guān)鍵和修飾作用的揮發(fā)性成分的種類沒(méi)有影響,而在高劑量組中(Z)-2壬烯醛、(Z)-2癸烯醛、2-己烯醛等物質(zhì)變?yōu)橹匾L(fēng)味成分,2-乙基呋喃、乙酸乙酯對(duì)風(fēng)味的貢獻(xiàn)減弱,可能是導(dǎo)致輻照異味的主要原因。利用3~5kGy電子束劑量前處理梅魚(yú)魚(yú)糜,能較好地保持魚(yú)糜凝膠風(fēng)味,而高劑量輻照會(huì)導(dǎo)致輻照異味的產(chǎn)生。試驗(yàn)結(jié)果為利用電子束輻照前處理改善魚(yú)糜凝膠品質(zhì)提供了依據(jù)。

    Abstract:

    Collichthys lucidus is an important raw material for surimi production. Well known as one of the effective cold sterilization methods, electron irradiation has been widely used in industrial food preservation, as well as in food quality improvement, food safety, and other allied fields in many countries. Some studies indicated that electron irradiation can change the conformation of surimi proteins, leading to protein denaturation, aggregation and gelation. Thus the quality of surimi gel will be improved by using electron beam irradiation pre-treatment. The purpose was to investigate the influence of electron beam irradiation on the smell of surimi gel. Using gas chromatography-mass spectrometry (GC-MS) and relatively odor activity value (ROAV), the effect of different electron beam dose on the volatile flavor components of Collichthys lucidus surimi gel was studied. The sensory evaluation in association with electronic nose was applied to confirm the optimal dose, which can effectively maintain the original flavor of surimi gel. The results showed that the fish smell of gel derived from surimi irradiated was slightly reduced, and a little bit of irradiation odor was presented in high-dose group (≥7kGy). Compared with the control and irradiation groups, the difference of linear discriminant analysis (LDA) by electronic nose was obvious. The overlap of LDA between groups of 3kGy and 5kGy showed these two groups had similar odor characteristics, so did groups of 7kGy and 9kGy. After dealing with different irradiation doses, the species of volatile flavor compound and the relative contents of hydrocarbons, aldehydes and ketones from surimi gel were increased. Decanal, 1-octen-3-ol, 3-methyl-butanal and 2,3-octanedione were the key odor compounds of surimi gel. There was little influence of electron beam irradiation with low-dose (less than or equal to 5kGy) on the key and modify odor compounds of surimi gel. When the irradiation dose was more than 7kGy, (Z)-2-nonenal, (Z)-2-decene aldehyde, 2-hexenal in the surimi gel became important flavor components, the contribution to the flavor of ethyl acetate and 2-ethyl-furan was significantly reduced, it was likely to be the leading cause of the irradiation odor. In conclusion, 3~5kGy of electron beam irradiation dose, the original flavor of Collichthys lucidus surimi gel can be effectively maintained, but high dose (more than or equal to 7kGy) of irradiation would cause the generation of special off-odor. The results can provide some theoretical basis for using electron beam irradiation pre-treatment to improve the quality of surimi gel.

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楊文鴿,鄧思瑤,呂梁玉,徐大倫,樓喬明,傅佳.電子束輻照前處理對(duì)梅魚(yú)魚(yú)糜凝膠揮發(fā)性成分的影響[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2017,48(9):344-351. YANG Wen’ge, DENG Siyao, Lü Liangyu, XU Dalun, LOU Qiaoming, FU Jia. Effects of Electron Beam Irradiation Pre-treatment on Volatile Flavor Components of Collichthys lucidus Surimi Gel[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(9):344-351.

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  • 收稿日期:2017-02-21
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  • 在線發(fā)布日期: 2017-09-10
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