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廢棄地復(fù)墾土壤重金屬空間格局及其與復(fù)墾措施的關(guān)系
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國家自然科學(xué)基金項(xiàng)目(41471186、41571217)和國家重點(diǎn)研發(fā)計(jì)劃項(xiàng)目(2016YFD0300801)


Spatial Pattern of Heavy Metal in Reclaimed Soil of Wasteland and Its Relationship to Reclamation Measures
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    摘要:

    基于經(jīng)典統(tǒng)計(jì)學(xué)、變異函數(shù)理論以及經(jīng)驗(yàn)貝葉斯克里格法,以西南地區(qū)某歷史遺留硫磺礦廢棄地為研究對(duì)象,從點(diǎn)與區(qū)域兩方面系統(tǒng)分析其復(fù)墾土壤重金屬空間分布特征,揭示其與復(fù)墾措施的量化關(guān)系。結(jié)果表明,經(jīng)典統(tǒng)計(jì)學(xué)、變異函數(shù)理論以及經(jīng)驗(yàn)貝葉斯克里格法相結(jié)合方法用于揭示硫磺礦廢棄地復(fù)墾土壤重金屬空間分布格局是可行和科學(xué)的。該硫磺礦廢棄地復(fù)墾土地的5種土壤重金屬的變異系數(shù)均較大,這與復(fù)墾土壤無序、易變以及空間均勻性和突變性統(tǒng)一的特征相符合。土壤重金屬富集系數(shù)均在2以上。在歷史礦山開采、復(fù)墾措施和地形地貌的共同作用下,不同土壤重金屬在全局空間上具有一定的相似,在南北和東西方向均基本呈現(xiàn)兩頭低和中間高的倒U字形趨勢(shì)。絕大多數(shù)復(fù)墾土壤重金屬的塊基比在50%,復(fù)墾過程中覆土、培肥和土壤pH值調(diào)節(jié)措施等隨機(jī)因素在各重金屬的空間變異中占主導(dǎo)作用。無論是何種重金屬,一區(qū)東部、二區(qū)北部、四區(qū)西部均呈現(xiàn)較高的重金屬含量;一區(qū)和二區(qū)西部、三區(qū)北部地區(qū)含量相對(duì)較低。復(fù)墾為林地和草地的重金屬平均含量均高于耕地,對(duì)于復(fù)墾為耕地后續(xù)需進(jìn)一步防控重金屬污染,特別是Cd元素;隨著有效土層厚度的逐漸增加,土壤重金屬總體呈下降趨勢(shì)。有效土層厚度在30~100cm之間土壤重金屬無明顯差異,建議研究區(qū)復(fù)墾覆土后有效土層厚度達(dá)到100cm以上。隨著土壤pH值變小,復(fù)墾土壤重金屬總體呈上升趨勢(shì),通過調(diào)控pH值來降低土壤重金屬含量需要持續(xù)保證在一定范圍,建議研究區(qū)pH值持續(xù)控制在7~8。

    Abstract:

    At present, the study about historical mining wasteland as the object, the spatial distribution characteristics of reclamation soil quality and the relationship between the spatial distribution characteristics of soil quality and the response to reclamation measures are rarely reported in the literature. Based on classical statistics, variation function theory and empirical Bayesian Kriging method, the southwest area of historical sulfur mining wasteland reclamation area as the research object, from two aspects of point and area, the spatial distribution characteristics of reclamation soil heavy metals were systematically analyzed, and the quantitative relationship between them and reclamation measures was revealed. The results showed that the combined method of classical statistics, geostatistics and empirical Bayesian Kriging was feasible to reveal the spatial distribution characteristics of soil heavy metals. The variation coefficients of heavy metals in the five soils were larger, which were consistent with the characteristics disorder, the variability and the spatial uniformity and the abrupt change of land reclamation. The enrichment coefficient of heavy metals in soil was more than 2. Under the interaction of mining, reclamation measures and topography interaction, the heavy metals in different soils had a certain similarity in the global space, in the northsouth and eastwest basically showed two low and high in the middle of the inverted “U” trend. The C0/(C0+C1) of most heavy metals of reclaimed soils was 50%, and the random factors, such as soil cover, soil fertility and soil pH value regulation, were dominant in the spatial variation of different heavy metals. No matter what kind of heavy metals, the eastern of the first region, the northern of the second region, and the western of the fourth region had higher heavy metal content;the western of the first and second regions, the northern of the third region was relatively low. The average content of heavy metals in forest land and grassland was higher than that of cultivated land, and the heavy metal pollution, especially the Cd, was needed to control the heavy metal pollution in the future. With the increase of the effective soil layer thickness, the heavy metals in the soil showed a decreasing trend. There was no significant difference of soil heavy metal between the effective soil layer thickness in 30~100cm, which suggested that the effective soil layer thickness of the reclaimed soil in the study area was 100cm or more. As soil pH value became smaller, the total heavy metals in reclaimed soil showed an increasing trend, but the control of pH value to reduce the content of heavy metals in soil needed to be maintained at a certain extent, the pH value of proposed study area was continuously controlled in 7 ~ 8. The research results would provide guidance on the method of quality monitoring for the reclamation of abandoned industrial and mining land, and provide a scientific basis for historical mining wasteland reclamation soil heavy metal pollution further control and management.

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張世文,周妍,羅明,周旭,崔紅標(biāo),黃元仿.廢棄地復(fù)墾土壤重金屬空間格局及其與復(fù)墾措施的關(guān)系[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2017,48(12):237-247. ZHANG Shiwen, ZHOU Yan, LUO Ming, ZHOU Xu, CUI Hongbiao, HUANG Yuanfang. Spatial Pattern of Heavy Metal in Reclaimed Soil of Wasteland and Its Relationship to Reclamation Measures[J]. Transactions of the Chinese Society for Agricultural Machinery,2017,48(12):237-247.

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  • 收稿日期:2017-04-06
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  • 在線發(fā)布日期: 2017-12-10
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