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發(fā)酵秸稈碎料內(nèi)乙醇平面熱源法提取及其設(shè)備設(shè)計(jì)
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國(guó)家重點(diǎn)研發(fā)計(jì)劃項(xiàng)目(2017YFC0210303、2016YFB0601305)


Extraction and Equipment Design of Ethanol Separation from Solid-state Fermented Crushed Straw Material by Planar Thermal Source
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    摘要:

    為降低固態(tài)發(fā)酵后秸稈碎料料內(nèi)乙醇提取能耗,用平面熱源進(jìn)行乙醇提取并設(shè)計(jì)相應(yīng)設(shè)備,進(jìn)行初步計(jì)算。基于熱重試驗(yàn),研究了固態(tài)發(fā)酵后的甜高粱稈粉碎料中乙醇的蒸餾規(guī)律??紤]料含濕量、濕分乙醇體積分?jǐn)?shù)、加熱溫度對(duì)料中濕分質(zhì)量變化速率的影響,得出在研究范圍內(nèi)(含濕量10%~90%,濕分乙醇體積分?jǐn)?shù)3%~11%,加熱溫度20~100℃)料中濕分質(zhì)量變化速率與乙醇體積分?jǐn)?shù)關(guān)系不大,隨料含濕量呈線性關(guān)系,隨加熱溫度呈冪函數(shù)關(guān)系,并得出回歸模型。基于乙醇揮發(fā)數(shù)據(jù),得出乙醇揮發(fā)數(shù)學(xué)模型?;谝陨蟽赡P?,推導(dǎo)出平面熱源提取乙醇的乙醇提取率方程,根據(jù)加熱溫度、料含濕量和濕分乙醇體積分?jǐn)?shù),便可計(jì)算任意時(shí)刻的乙醇提取率。建立成本模型并進(jìn)行成本分析發(fā)現(xiàn),該提取方法成本顯著低于原有蒸汽提醇法。最后設(shè)計(jì)了一套采用平面熱源連續(xù)提取發(fā)酵料內(nèi)乙醇的生產(chǎn)裝置,給出其設(shè)計(jì)計(jì)算式,進(jìn)行了初步設(shè)計(jì),得到一套示例性質(zhì)的工業(yè)級(jí)設(shè)備方案。

    Abstract:

    Annual production of straw is 600~800 million tons in China. The advanced solidstate fermentation technology (ASSF) and solidstate fermented crushed straw material had been developed to acquire ethanol and increase the economical utilization level of straw. However, the high cost of ethanol separation from fermented material is the biggest problem unsolved. Planar thermal source (PTS) was used to separate ethanol from solidstate fermented crushed straw material (SSFM) instead of water steam. In order to facilitate the study, fermented material and dry material uniformly added with ethanol solution were heated on thermal balance under the same environmental condition. The mass, wet content, ethanol concentration in wet of control group and test group were the same. The mass loss curve of them was familiar. As a result, from the macro view, dry material uniformly added with ethanol solution (called prepared material) can be used on study instead of fermented material, which made it easier to study quantitatively. Complete thermogravimetric test was done on prepared material to study the material wet change rules. Factors considered were heating temperature T(20~100℃), wet content θ (10%~90%), ethanol concentration in wet ω (3%~11%). The weight order of factors on material wet change speed Vloss,e in descending trend was T, θ and ω, and ω can be ignored for that was an order of magnitude less important than the other factors. Vloss,e was linearly increased with the increase of T, and increased by power function with the increase of θ. Vloss,e model with T and θ was regressed. As there was no chemically combined water in prepared material, heating material can be considered as heating ethanol solution in materialshaped electric heating device. According to multi data, equations for ethanol solution evaporation coefficient K were derived. Above all, model of ethanol separation from SSFM by PTS was derived. The cost model was added at last. Software was programmed to calculate the separation process and its cost. The result showed that the cost of PTS method was obviously lower than that of the current water steam method. The new method would significantly promote the ASSF technology to produce renewable energy. The study can also be used as reference on drying process of other crushed plant material. In the end, a set of production equipment for continuous ethanol separation from fermented material by PTS was given. The design formulas were given and a sample set of industrial level equipment was calculated.

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周敬之,馮俊小.發(fā)酵秸稈碎料內(nèi)乙醇平面熱源法提取及其設(shè)備設(shè)計(jì)[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2018,49(5):330-341. ZHOU Jingzhi, FENG Junxiao. Extraction and Equipment Design of Ethanol Separation from Solid-state Fermented Crushed Straw Material by Planar Thermal Source[J]. Transactions of the Chinese Society for Agricultural Machinery,2018,49(5):330-341.

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  • 收稿日期:2017-11-02
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  • 在線發(fā)布日期: 2018-05-10
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