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復(fù)合吸波劑TiC/SiC誘導(dǎo)微波熱解生物質(zhì)試驗研究
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國家自然科學(xué)基金項目(51806186)、江蘇省動力機(jī)械清潔能源與應(yīng)用重點實驗室開放基金項目(QK17007)和鹽城工學(xué)院引進(jìn)人才校級科研基金項目(XJ201708)


Experiment on Microwave Pyrolysis of Biomass Induced by Compound Absorber
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    摘要:

    采用復(fù)合吸波劑TiC/SiC進(jìn)行了生物質(zhì)微波熱解制備生物油有機(jī)相的研究。采用響應(yīng)面法分析了TiC與SiC質(zhì)量百分比、吸波劑與生物質(zhì)質(zhì)量百分比和微波功率與生物質(zhì)質(zhì)量比對有機(jī)相產(chǎn)率的影響;在最優(yōu)工藝條件下,對比分析了采用純SiC和復(fù)合吸波劑對有機(jī)相產(chǎn)率及化學(xué)組成的影響,并對固體產(chǎn)物生物焦進(jìn)行了表征,分析了有機(jī)相和生物焦的性能及潛力。結(jié)果表明,各因素對有機(jī)相產(chǎn)率影響顯著,且相互間存在交互影響;當(dāng)TiC與SiC質(zhì)量百分比為20%、吸波劑與生物質(zhì)質(zhì)量百分比為53%和微波功率與生物質(zhì)質(zhì)量比為9.5W/g時,有機(jī)相產(chǎn)率達(dá)到28.60%,與預(yù)測值28.69%較為接近。使用純SiC作為吸波劑時,有機(jī)相產(chǎn)率降至23.35%,說明引入適量TiC可以使生物質(zhì)熱解更多地保留來自纖維素和半纖維素的產(chǎn)物,在增加有機(jī)相產(chǎn)率的同時,降低酸類、酮類和酚類相對含量;相對較多的呋喃類、醇類和酚類及其相對集中的碳原子數(shù)分布,使所得有機(jī)相產(chǎn)物可用作精細(xì)化工原料;核磁共振分析表明,使用復(fù)合吸波劑所得有機(jī)相中脂肪氫/碳比與芳香氫/碳比明顯升高,驗證了分析的準(zhǔn)確性;復(fù)合吸波劑使生物焦具有更高的碳化程度和吸附性能,比表面積和孔容達(dá)360m2/g和0.22cm3/g,可制成活性材料。

    Abstract:

    Bio-oil organic phases were prepared by microwave pyrolysis of biomass with the compound absorber of TiC/SiC. The effects of mass ratios of TiC to SiC, absorber to biomass and microwave power to biomass on the yield of organic phase were analyzed by response surface methodology. The effects of pure SiC and compound absorber on the yields and chemical compositions of organic phase were analyzed and compared under the optimal conditions, and the characterization and analysis of bio-char were also carried out, to explore the properties and potential of organic phase and bio-char. The results showed that all factors had obvious effects on organic yield with interactions between the factors. The optimal yield was 28.60% under conditions of TiC to SiC mass ratio of 20%, absorber to biomass mass ratio of 53% and microwave power to biomass mass ratio of 9.5W/g, which was similar to the predicted value of 28.69%. When the pure SiC was used under the optimal conditions, the organic yield was reduced to 23.35%. The pyrolysis products from cellulose and hemicellulose could be retained more by introducing appropriate amount of TiC, which could increase the organic yield and reduce the relative content of acids, ketones and phenols at the same time. A relatively large number of furans, alcohols and phenols and their relatively concentrated carbon atom distribution made organic phase have high potential as chemical raw materials. The NMR analysis showed that the ratio of aliphatic hydrogen/carbon to aromatic hydrogen/carbon in organic phase obtained by using compound absorber was increased significantly, which verified the accuracy of the analysis. In addition, the bio-char obtained by using the compound absorber had higher carbonization degree and adsorption performance, and its specific surface area and pore volume were 360m2/g and 0.22cm3/g respectively. It had high potential to make active materials. The research result provided experimental and theoretical basis for further industrial application research.

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樊永勝,侯光喜,熊永蓮,蔡憶昔,趙衛(wèi)東.復(fù)合吸波劑TiC/SiC誘導(dǎo)微波熱解生物質(zhì)試驗研究[J].農(nóng)業(yè)機(jī)械學(xué)報,2020,51(5):331-338. FAN Yongsheng, HOU Guangxi, XIONG Yonglian, CAI Yixi, ZHAO Weidong. Experiment on Microwave Pyrolysis of Biomass Induced by Compound Absorber[J]. Transactions of the Chinese Society for Agricultural Machinery,2020,51(5):331-338.

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  • 收稿日期:2019-10-09
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  • 在線發(fā)布日期: 2020-05-10
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