亚洲一区欧美在线,日韩欧美视频免费观看,色戒的三场床戏分别是在几段,欧美日韩国产在线人成

尿素預(yù)處理玉米秸稈降解木質(zhì)素動(dòng)力學(xué)研究
作者:
作者單位:

作者簡(jiǎn)介:

通訊作者:

中圖分類(lèi)號(hào):

基金項(xiàng)目:

國(guó)家自然科學(xué)基金項(xiàng)目(51406032)、東北農(nóng)業(yè)大學(xué)“學(xué)術(shù)骨干”項(xiàng)目(18XG15)、中央引導(dǎo)地方科技發(fā)展專(zhuān)項(xiàng)(ZY17C05)和黑龍江省博士后科研啟動(dòng)基金項(xiàng)目(LBH-Q19008)


Delignification Kinetics of Corn Stover with Urea Pretreatment
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 圖/表
  • |
  • 訪問(wèn)統(tǒng)計(jì)
  • |
  • 參考文獻(xiàn)
  • |
  • 相似文獻(xiàn)
  • |
  • 引證文獻(xiàn)
  • |
  • 資源附件
  • |
  • 文章評(píng)論
    摘要:

    為探究尿素預(yù)處理玉米秸稈降解木質(zhì)素的動(dòng)力學(xué)特性,解析尿素對(duì)玉米秸稈木質(zhì)素的作用規(guī)律,研究了總固體質(zhì)量分?jǐn)?shù)(10%、30%、50%和70%)和尿素添加比例(1∶100、1∶20、1∶10、1∶2和7∶10)對(duì)玉米秸稈木質(zhì)素含量的影響,并進(jìn)行模型擬合,獲得了尿素預(yù)處理玉米秸稈降解木質(zhì)素動(dòng)力學(xué)模型。結(jié)果表明:總固體質(zhì)量分?jǐn)?shù)在50%以內(nèi)時(shí),隨著尿素添加比例的增加,玉米秸稈的木質(zhì)素去除率先增加、后降低,總固體質(zhì)量分?jǐn)?shù)為70%時(shí)木質(zhì)素去除率隨著尿素添加比例的增加而增加,當(dāng)總固體質(zhì)量分?jǐn)?shù)為10%和70%、對(duì)應(yīng)尿素添加比例為1∶20和7∶10時(shí),獲得的最大木質(zhì)素去除率分別為71.05%、68.69%;不同預(yù)處理?xiàng)l件下,玉米秸稈的殘余木質(zhì)素質(zhì)量與總固體回收量均呈現(xiàn)較好的線性關(guān)系,在整個(gè)尿素預(yù)處理過(guò)程中脫木質(zhì)素選擇性系數(shù)穩(wěn)定在0.32~0.48g/g之間;尿素預(yù)處理玉米秸稈的脫木質(zhì)素過(guò)程符合初始脫木質(zhì)素、大量脫木質(zhì)素和殘余脫木質(zhì)素3個(gè)階段連續(xù)一階動(dòng)力學(xué)模型,大量脫木質(zhì)素階段的最大可脫除木質(zhì)素質(zhì)量比可達(dá)0.71,在低、高總固體含量下,尿素轉(zhuǎn)化的液態(tài)銨和氣態(tài)氨對(duì)玉米秸稈均具有較好的脫木質(zhì)素作用。

    Abstract:

    Urea is easily dissolved in water and converted into gaseous ammonia or ammonium and bicarbonate ions under the catalysis of urease. The effects of total solids (10%, 30%, 50% and 70%) and ratios of urea to corn stover (1∶100, 1∶20, 1∶10, 1∶2 and 7∶10) on residual lignin content of corn stover were studied systematically at 75℃ to achieve the delignification kinetics of urea-pretreated corn stover, and the urea pretreatment characteristics of corn stover at different total solids were compared. The delignification kinetics characteristics of corn stover during urea pretreatment were fitted based on three first-order reactions. The first, second and third terms were based on the initial, bulk and residual phases of delignification, respectively. The results showed that the residual lignin content of urea-pretreated corn stover was decreased as the ratio of urea to corn stover was increased firstly, reached minimum and then increased as the ratio of urea to corn stover was increased when total solids was less than 50%. In comparison, the residual lignin content of urea-pretreated corn stover was decreased as the ratio of urea to corn stover was increased during pretreatment with total solids of 70%. The two optimal lignin removal rates of 71.05% and 68.69% were achieved at total solids of 10% and 70% with urea to corn stover ratios of 1∶20 and 7∶10, respectively. A good linear relationship between the residual lignin content of urea-pretreated corn stover and the solid recovery yield was obtained under different pretreatment conditions. The delignification selectivity of ureapretreated corn stover was stable at 0.32~0.48g/g during pretreatment process. The delignification kinetics of urea-pretreated corn stover conformed to the three first-order models of initial, bulk and residual phases. The maximum delignification fraction of the bulk-phase reached up to 0.71. Therefore, the aqueous or gaseous ammonia converted from urea at low or high total solids were equally favorable for the delignification of corn stover. The results provided good insights into the urea pretreatment of lignocellulosic biomass.

    參考文獻(xiàn)
    相似文獻(xiàn)
    引證文獻(xiàn)
引用本文

王忠江,鄒艦洋,曹振,王麗麗,劉卓,李一博.尿素預(yù)處理玉米秸稈降解木質(zhì)素動(dòng)力學(xué)研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2020,51(11):321-328. WANG Zhongjiang, ZOU Jianyang, CAO Zhen, WANG Lili, LIU Zhuo, LI Yibo. Delignification Kinetics of Corn Stover with Urea Pretreatment[J]. Transactions of the Chinese Society for Agricultural Machinery,2020,51(11):321-328.

復(fù)制
分享
文章指標(biāo)
  • 點(diǎn)擊次數(shù):
  • 下載次數(shù):
  • HTML閱讀次數(shù):
  • 引用次數(shù):
歷史
  • 收稿日期:2020-01-14
  • 最后修改日期:
  • 錄用日期:
  • 在線發(fā)布日期: 2020-11-10
  • 出版日期: 2020-11-25
文章二維碼