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不同超聲條件下結(jié)冷膠酸性凝膠的凝膠特性研究
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“十三五”國(guó)家重點(diǎn)研發(fā)計(jì)劃重點(diǎn)專項(xiàng)(2019YFD0901604)和國(guó)家自然科學(xué)基金項(xiàng)目(51103131)


Effects of High Intensity Ultrasound on Acid Induced Gelation Properties of Gellan Gels
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    利用高能超聲波處理低?;Y(jié)冷膠(Low acyl gellan gum,LA)水溶液,并以葡萄糖酸-δ-內(nèi)酯(Glucono-δ-lactone,GDL)為酸誘導(dǎo)劑制備了結(jié)冷膠酸性凝膠,以不透明指數(shù)、斷裂應(yīng)力、斷裂應(yīng)變、楊氏模量、保水性指數(shù)為指標(biāo),考察了超聲作用對(duì)結(jié)冷膠酸性凝膠凝膠特性的影響。結(jié)果表明,結(jié)冷膠濃度越高,斷裂應(yīng)力、楊氏模量、不透明指數(shù)和保水性越大,斷裂應(yīng)變則越小。超聲時(shí)間越長(zhǎng),超聲功率越大,凝膠的斷裂應(yīng)變?cè)酱?,但斷裂?yīng)力、楊氏模量則越小。斷裂應(yīng)力、楊氏模量隨著GDL/LA質(zhì)量比的增大出現(xiàn)了先增加后降低的變化趨勢(shì),當(dāng)GDL/LA質(zhì)量比為1時(shí)取得最大值。GDL/LA質(zhì)量比增大,酸性凝膠的斷裂應(yīng)變和保水性減小,而不透明指數(shù)增大。保水性隨著超聲功率的增大而降低,但隨著超聲時(shí)間的延長(zhǎng),保水性出現(xiàn)了小幅提高,當(dāng)超聲時(shí)間為30min時(shí),保水性最大。超聲處理使結(jié)冷膠分子鏈斷鏈,凝膠三維網(wǎng)絡(luò)結(jié)構(gòu)中形成了懸掛鏈,凝膠強(qiáng)度降低。結(jié)冷膠濃度越大,凝膠的微觀結(jié)構(gòu)越致密。超聲處理可用于結(jié)冷膠改性以改善其凝膠特性。

    Abstract:

    Gellan gum is commonly used as a food ingredient because of its gelling and thickening properties. Application of high intensity ultrasound (HIUS) in food industry is currently attracting much attention because it can be used to alter food physical or chemical properties with a low impact on the environment. Gellan gum solution was subjected to high intensity ultrasound at 55℃ (above the sol-gel transition temperature) before acdification to determine the effectes of HIUS on glucono-δ-lactone (GDL) induced gelation properties of low acyl gellan gels (LA). The results showed that with the increase of gellan concentration, fracture stress, initial Youngs modulus, the opacity index and water holding capacity were increased, but fracture strain was decreased. With the increase of ultrasonic time and ultrasonic power, the fracture stress and initial Youngs modulus were decreased, while the fracture strain was increased. The fracture stress and initial Youngs modulus were firstly increased and then decreased with the increase of GDL/LA weight ratio. The optimum GDL/LA weight ratio to the gel strength for the acid gels was about 1. As the GDL/LA weight ratio was increased, fracture strain and the water holding capacity were decreased while the opacity index was increased. The reduction in gel strength was attributed to the reduced chain length of the gellan polymer molecules and the gel network may include dangling chains which did not contribute to elasticity. The higher the gellan concentration was, the more dense microstructures were. The results indicated that high intensity ultrasound could be used for modifying gellan gum to improve its gelling properties.

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陳青,程紅梅,周濤濤,岳志敏,韓曉祥.不同超聲條件下結(jié)冷膠酸性凝膠的凝膠特性研究[J].農(nóng)業(yè)機(jī)械學(xué)報(bào),2021,52(10):402-408. CHEN Qing, CHENG Hongmei, ZHOU Taotao, YUE Zhimin, HAN Xiaoxiang. Effects of High Intensity Ultrasound on Acid Induced Gelation Properties of Gellan Gels[J]. Transactions of the Chinese Society for Agricultural Machinery,2021,52(10):402-408.

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  • 收稿日期:2020-10-29
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  • 在線發(fā)布日期: 2021-03-02
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